![]() You will find examples on pages 260 to the top of page 262, and in problems 15 and 16 in the end-of-chapter questions. There are lots in my calculations book if you have a copy. That's because there is a decrease in the total number of gas molecules present.Īnd that is all there is to it! You will, of course, need to practise doing this until you are completely confident, but you will need to find your own examples. The entropy has decreased - as we predicted it would in the earlier page. Total entropy at the end = 214 + 2(69.9) = 353.8 J K -1mol -1Įntropy change = what you end up with - what you started with.Įntropy change = 353.8 - 596 = -242.2 J K -1mol -1 You ended up with 1 mole of carbon dioxide and two moles of liquid water. You started with 1 mole of methane and 2 moles of oxygen. In the introductory page we looked at the following reaction and worked out that there would be a decrease in entropy. Where Σ (sigma) simply means "the sum of". Change in entropy = what you end up with - what you started with You add up the entropies for everything you end up with, and take away the entropies of everything you started with. ![]() Working out entropy changes for a reaction is very easy. In an exam, you will be given values for all the standard entropies you need. The thing you must be most careful about is the fact that entropy is measured in joules, not kilojoules, unlike most of the other energy terms you will have come across. Use whatever units the examiners give you. 1 bar is 100 kPa 1 atmosphere is 101.325 kPa. Don't worry about it - they are nearly the same. You might find the pressure quoted as 1 atmosphere rather than 1 bar in less recent sources. If your syllabus doesn't mention all these different sorts, just ignore this comment.Įntropy is given the symbol S, and standard entropy (measured at 298 K and a pressure of 1 bar) is given the symbol S°. Entropy change to the surroundings and the total entropy change are dealt with on another page. This page deals only with entropy changes to the system. Note: If you haven't already read the page about introducing entropy, you should do so before you go on. This page looks at how you can calculate entropy changes during reactions from given values of entropy for each of the substances taking part.
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How is it, then, that I could not put down Graham Moore’s The Last Days of Night? I don’t grasp the principles of electricity, and to be honest I don’t give them much thought. If you ask me how electricity is generated, you will hear crickets chirping. Patrick Anderson regularly reviews mysteries and thrillers for The Washington Post.Rating: An illuminating look at the compulsion of invention Moore’s book demonstrates this point well, and his intellectual curiosity, graceful prose and tireless research have made “ The Last Days of Night” a model of superior historical fiction. For good or ill, human inventiveness is inexhaustible. Salesmen like Edison.” He mentions other innovators then emerging, including Henry Ford and the Wright brothers. Although, if Cravath was buying, he did sometimes enjoy lobster and good wine at Delmonico’s.Īs the story ends, Cravath looks back on the birth of electricity - the world-changing “end of night” - and concludes that “in order to produce such a wonder the world required men like each of them. ![]() When his work went well, Tesla would gladly live in furnished rooms and subsist on saltine crackers. He lived for ideas, solutions to problems, and was content to have lesser men implement them. In many ways, the inventor he most admires is the often bewildering Tesla, who cared not a whit for fame and fortune. He’s fascinated by the nature of genius and its remarkable flowering near the end of the 19th century. Ultimately, Moore’s novel addresses more than the epic battle between two great inventors. A detailed author’s note makes clear what is historical fact in the novel - most of the story - and what is fiction. Morgan finally wields his money like a bludgeon to force a settlement of the long war between Edison and Westinghouse. This romance really happened, although Moore admits embellishments. Cravath’s father, a clergyman, co-founded Fisk University in Nashville after the Civil War to provide education for freed slaves.Ĭravath himself engages in a cautious romance with the beautiful, formidable Agnes Huntington, who sang with the Metropolitan Opera. Cravath’s grandfather helped found Ohio’s Oberlin College to foster coeducation. The novel abounds with fascinating real-life characters. The horror that followed, although factual, is almost beyond belief. Soon enough, a condemned man was gagged and strapped into the first electric chair. He used his political influence to convince the New York legislature that electrocution - using the AC current - should replace hanging in carrying out the death penalty. Proof, Edison’s man declared, of the fate that might befall America’s children if Westinghouse had his way.Įdison did not stop with dogs. The DC power caused the dogs to yelp in pain the stronger AC voltage inflicted horrid deaths upon them. Edison, he knew, was not a man to cross.Įdison set out to persuade the country that his rival’s AC current was so dangerous that it would “murder your children.” He sent a man up and down the East Coast to hold public exhibitions at which DC and then AC power were sent through the bodies of dogs. Cravath, fearing that Edison might have Tesla killed - his laboratory did mysteriously burn down - kept him in hiding for months. He went to work for Westinghouse to perfect his invention. Tesla found a way to use the higher-voltage alternating current, or AC, to overcome the distance limit and thus revolutionize the spread of electricity. Unfortunately, DC could be transmitted only short distances, and therefore only those with enough money to buy a generator for their homes could enjoy electricity. At that point, Edison could offer only direct current, or DC, power. Cravath’s job was to persuade the courts that, despite the patent office ruling, his client’s bulb was different from Edison’s.Īnother inventor enters the story, the Serbian-born, highly eccentric, often unstable Nikola Tesla. Edison was demanding $1 billion in damages. patent office had ruled that Westinghouse’s bulb violated Edison’s patent. The legal case, simply put, was that Edison had patented a lightbulb and that Westinghouse had invented a better one, but the U.S. "The Last Days of Night" by Graham Moore (Random House) ![]() Themify also offers a selection of quality accessories and accessories. They can also be used on an unlimited number of websites.
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The cognitiveservices/v1 endpoint allows you to convert text to speech by using Speech Synthesis Markup Language (SSML). This status might also indicate invalid headers. There's a network or server-side problem. You have exceeded the quota or rate of requests allowed for your resource. Make sure your resource key or token is valid and in the correct region. A common reason is a header that's too long. Or, the value passed to either a required or optional parameter is invalid. ![]() HTTP status codeĪ required parameter is missing, empty, or null. The HTTP status code for each response indicates success or common errors. "LocaleName": "Chinese (Mandarin, Simplified)", "Name": "Microsoft Server Speech Text to Speech Voice (zh-CN, YunxiNeural)", "Name": "Microsoft Server Speech Text to Speech Voice (ga-IE, OrlaNeural)", "ShortName": "en-US-JennyMultilingualNeural", "Name": "Microsoft Server Speech Text to Speech Voice (en-US, JennyMultilingualNeural)", "Name": "Microsoft Server Speech Text to Speech Voice (en-US, JennyNeural)", This JSON example shows partial results to illustrate the structure of a response: [ The WordsPerMinute property for each voice can be used to estimate the length of the output speech. You should receive a response with a JSON body that includes all supported locales, voices, gender, styles, and other details. header 'Ocp-Apim-Subscription-Key: YOUR_RESOURCE_KEY' Here's an example curl command: curl -location -request GET '' \ Ocp-Apim-Subscription-Key: YOUR_RESOURCE_KEY This request requires only an authorization header: GET /cognitiveservices/voices/list HTTP/1.1 For more information, see Authentication.Įither this header or Ocp-Apim-Subscription-Key is required.Ī body isn't required for GET requests to this endpoint. This table lists required and optional headers for text-to-speech requests: HeaderĮither this header or Authorization is required.Īn authorization token preceded by the word Bearer. Voices and styles in preview are only available in three service regions: East US, West Europe, and Southeast Asia. ![]() Blow it up, then keep destroying the other walls behind it. On one of the floors is a wall that appears questionable. 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